Influence of ferric iron on phase equilibria in greenschist facies assemblages: the hematite‐rich metasedimentary rocks from the Monti Pisani (Northern Apennines)     

D. Lo Pò  R. Braga 《Journal of Metamorphic Geology》2014,32(4):371-387

We have investigated the effects of different Fe₂O₃ bulk contents on the calculated phase equilibria of low‐T/intermediate‐P metasedimentary rocks. Thermodynamic modelling within the MnO–Na₂O–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O (MnNKFMASHTO) chemical system of chloritoid‐bearing hematite‐rich metasedimentary rocks from the Variscan basement of the Pisani Mountains (Northern Apennines, Italy) fails to reproduce the observed mineral compositions when the bulk Fe₂O₃ is determined through titration. The mismatch between observed and computed mineral compositions and assemblage is resolved by tuning the effective ferric iron content by P–XFe₂O₃ diagrams, obtaining equilibration conditions of 475 °C and 9–10 kbar related to a post‐compressional phase of the Alpine collision. The introduction of ferric iron affects the stability of the main rock‐forming silicates that often yield important thermobaric information. In Fe₂O₃‐rich compositions, garnet‐ and carpholite‐in curves shift towards higher temperatures with respect to the Fe₂O₃‐free systems. The presence of a ferric‐iron oxide (hematite) prevents the formation of biotite in the mineral assemblage even at temperatures approaching 550 °C. The use of P–T–XFe₂O₃ phase diagrams may also provide P–T information in common greenschist facies metasedimentary rocks.  相似文献   

多年冻土工程地质制图的阶梯发展   总被引：2，自引：1，他引：1  

张中琼  林芳  吴青柏  张泽  张鹏 《冰川冻土》2021,43(1):176-183

多年冻土工程地质制图是区域和历史冻土学研究的基础内容之一。多年冻土工程地质制图是根据需要和制图原则,在特定时空尺度分析多年冻土特征,以及各种自然、工程、环境要素共同影响下的多年冻土属性的量化描述。多年冻土工程地质制图所解决的科学问题从多年冻土的分布、规律和格局、冻土功能,认识不断提高。制图的内容从研究多年冻土的基本要素,特征要素,到功能要素,制图的实用性不断增强。制图方法从基本地理和工程地质方法逐步发展到系统论方法。总之,多年冻土工程地质制图表现出时间尺度上阶段性和空间坐标上的台阶性,在认识的深度和广度上均不断深化。为多年冻土区基础科学研究、工程建设、寒区资源环境等方面的工作提供基础数据和技术支持。  相似文献   

多相糜棱岩内第二相对应变局部化的影响——以秦岭群花岗质糜棱岩为例     

韩宁  赵中宝  王根厚  孙丽静  巴合达尔·巴勒塔别克 《地质学报》2021,95(5):1614-1629

糜棱岩韧性变形发生的应变局部化过程,尤其是多相糜棱岩第二相对基质相变形的影响一直是显微构造研究难点.研究表明糜棱岩借助颗粒边界滑移实现多相混合,形成多矿物相集合体.在多相糜棱岩内,第二相在基质相颗粒边界施加齐纳阻力,牵制基质相颗粒边界的迁移速率,破坏基质相颗粒的动态平衡过程,使基质相颗粒位于古应力计对应的颗粒粒度以下,导致基质相整体的表面积增大,促进扩散交换过程,提高了扩散蠕变,降低了基质相位错蠕变和结晶学优选方位(CPO)形成的效率,使变形机制从颗粒粒径不敏感蠕变机制(GSI)过渡为颗粒粒径敏感蠕变机制(GSS).另外,多相糜棱岩内的第二相具有诱导应变局部化的效应,使塑性应变局部化更为强烈,引起物质强度的变化,进而引起岩石变形过程和岩石圈流变行为的改变.选取秦岭群花岗质糜棱岩进行多相矿物糜棱岩定量化研究,结果显示花岗质糜棱岩伴随着云母含量的增多以及各相混合程度的增大,石英的颗粒粒度明显减小,CPO强度显著降低,基质相显微变形受第二相控制逐渐增强.  相似文献   

全风化花岗岩地层中高固相离析浆液灌浆机理研究          下载免费PDF全文

赵钰  郑洪  曹函  林飞  王旭斌  贺茉莉 《水文地质工程地质》2021,48(2):78-88

全风化花岗岩地层稳定性差、遇水易发生崩解,工程上使用常规材料防渗加固注浆时效果较差。针对这一情况,依托湖南省郴州市莽山水库防渗加固灌浆项目,通过自主设计的全风化花岗岩地层注浆室内模拟试验装置,进行模拟注浆试验,实现了浆液在整个注浆过程中的扩散情况模拟,对不同注浆压力、不同位置点所取试样开展单轴抗压、抗剪强度及渗透率测试试验,对不同注浆压力下完整结石体取样观察,研究以全风化花岗岩颗粒为配方主体材料的高固相离析浆液在全风化花岗岩地层的防渗加固效果及浆液扩散模式。结果表明:该浆液在全风化花岗岩地层扩散过程中经历了渗透扩散、挤密压缩、劈裂扩展三个阶段,是一种复合注浆形式;以全风化花岗岩颗粒为主体的高固相离析浆液在全风化花岗岩地层注浆中效果显著,随着注浆压力提升,单轴抗压强度显著提升为原土体的3.25～13.67倍,抗剪强度在不同法向压力情况下提升为原土体的1.63～2.69倍,渗透系数从10?4 cm/s下降至10?5 cm/s甚至10?6 cm/s。  相似文献   

水合物地层低热固井水泥浆用相变微胶囊的制备及应用          下载免费PDF全文

杨国坤  汪爱明  尹舒婷  代天  刘天乐  蒋国盛 《探矿工程》2021,48(3):118-124

当深海固井遇到天然气水合物地层时,由于水泥浆水化放热,导致水合物的相变平衡条件发生改变,诱发水合物分解,引起二界面胶结质量下降等问题。为提高水合物地层固井质量,可向水泥浆中添加具有吸热控温作用的相变微胶囊,可有效降低固井水泥浆的水化升温。基于此,以配比石蜡为控温芯材、碳酸钙为壁材,利用自组装法制备了一种使用于深水水合物地层固井水泥浆控温微胶囊。由于固井水泥浆在达到水合物地层的过程中,外界温度环境复杂,单一相变温度的控温芯材极易失效。为扩展控温区间,选用切片石蜡与白油作为混合芯材,控温区间达到14.8~39.8 ℃。研究表明,该微胶囊表观形态良好、彼此无团聚,在热循环过程中,不易发生泄漏。与水泥浆复配后,对水泥浆流变性能无明显影响。在低掺加量时,微胶囊主要起降低水泥浆峰值温度的效果,并提升水泥石整体力学强度;高掺加量时,微胶囊既可以有效降低水泥浆峰值温度,也可以明显地延缓水泥浆放热速率。  相似文献   

CINRAD-SA双偏振雷达资料在降水估测中的应用初探   总被引：2，自引：0，他引：2       下载免费PDF全文

陈超  胡志群  胡胜  张扬  李珊珊 《气象》2019,45(1):113-125

对基于水平反射率ZH和差分传播相移率K_(DP)的降水估测综合法R(C)进行了改进,并对广州S波段双偏振雷达2016年2次飑线和2次台风降水过程的Φ_(DP)使用小波分析进行滤波处理,在此基础上使用变距最小二乘法拟合得到K_(DP)的值。分别使用R(C)和R(Z_H)法对2次飑线和2次台风降水过程进行降水估算,将估算结果和雨量计小时雨量进行了对比,并将两种方法的评估结果进行了对比。结果表明:(1)对于飑线类型降水,R(C)法对5 mm·h~(-1)以上的降水估测精度要好于R(Z_H)法,且降水率越大,R(C)法优势越明显,当降水率≥20 mm·h~(-1)时,两次过程R(C)法比R(Z_H)法的平均相对误差(RE)降低了17. 2%,平均绝对误差(AE)减少了1.89 mm,平均均方根误差(RMSE)减少了1.66 mm;(2)对于台风类型降水,R(C)法对5 mm·h~(-1)以上的降水估测精度也好于R(Z_H)法,当降水率≥20 mm·h~(-1)时,两次过程R(C)法比R(Z_H)法的平均RE降低了33. 19%,平均AE减少了3. 95 mm,平均RMSE减少了4.05 mm;(3)对于飑线和台风两种类型降水R(C)法都明显改善了降水率较大时的R(Z_H)法低估问题,但R(C)法在降水率10 mm·h~(-1)时也存在低估,可能是由雨滴谱资料观测误差导致拟合的系数偏小或雷达硬件造成的观测偏差等造成的。  相似文献   

Does continental crust transform during eclogite facies metamorphism?   总被引：1，自引：0，他引：1       下载免费PDF全文

D. J. Young  A. R. C. Kylander‐Clark 《Journal of Metamorphic Geology》2015,33(4):331-357

Eclogites within exhumed continental collision zones indicate regional burial to depths of at least 60 km, and often more than 100 km in the coesite‐stable, ultra‐high pressure (UHP) eclogite facies. Garnet, omphacitic pyroxene, high‐Si mica, kyanite ± coesite should grow at the expense of low‐P minerals in most felsic compositions, if equilibrium obtained at these conditions. The quartzofeldspathic rocks that comprise the bulk of eclogite facies terranes, however, contain mainly amphibolite facies, plagioclase‐bearing assemblages. To what extent these lower‐P minerals persisted metastably during (U)HP metamorphism, or whether they grew afterwards, reflects closely upon crustal parameters such as density, strength and seismic character. The Nordfjord area in western Norway offers a detailed view into a large crustal section that was subducted into the eclogite facies. The degree of transformation in typical pelite, paragneiss, granitic and granodioritic gneiss was assessed by modelling the equilibrium assemblage, comparing it with existing parageneses in these rocks and using U/Th–Pb zircon geochronology from laser ablation ICPMS to establish the history of mineral growth. U–Pb dates define a period of zircon recrystallization and new growth accompanying burial and metamorphism lasting from 430 to 400 Ma. Eclogite facies mafic rock (~2 vol.% of crust) is the most transformed composition and records the ambient peak conditions. Rare garnet‐bearing pelitic rocks (<10 vol.% of crust) preserve a mostly prograde mineral evolution to near‐peak conditions; REE concentrations in zircon indicate that garnet was present after 425 Ma and feldspar broke down after 410 Ma. Felsic gneiss – by far the most abundant rock type – is dominated by quartz + biotite + feldspar, but minor zoisite/epidote, phengitic white mica, garnet and rutile point to a prograde HP overprint. Relict textures indicate that much of the microstructural framework of plagioclase, K‐feldspar, and perhaps biotite, persisted through at least 25 Ma of burial, and ultimately UHP metamorphism. The signature reaction of the eclogite facies in felsic rocks – jadeite/omphacite growth from plagioclase – cannot be deduced from the presence of pyroxene or its breakdown products. We conclude that prograde dehydration in orthogneiss leads to fluid absent conditions, impeding equilibration beyond ~high‐P amphibolite facies.  相似文献   

Grampian migmatites in the Buchan Block,NE Scotland   总被引：1，自引：0，他引：1       下载免费PDF全文

T. E. Johnson  C. L. Kirkland  S. M. Reddy  S. Fischer 《Journal of Metamorphic Geology》2015,33(7):695-709

Rocks exposed along the Scottish coast between Fraserburgh and Inzie Head contain information critical to understanding the evolution of the Buchan Block, the type locality for low‐P, high‐T regional metamorphism, and its relationship with the rest of the Grampian terrane, one of the major tectonostratigraphic components of the Scottish Caledonides. The ~8 km long section traverses a regional network of shear zones and, at the highest grades around Inzie Head, passes into the core of the Buchan Anticline, a large‐scale open fold that is commonly regarded as a late structure, post‐dating metamorphism. The metasedimentary rocks increase in grade from upper amphibolite to granulite facies and preserve unequivocal evidence for partial melting. The diatexite migmatites around Inzie Head, along with other gneissose units within the Buchan Block, have been regarded as allochthonous Precambrian basement rocks that were thrust into their current position during the Grampian orogenesis. However, field observations show that the onset of in situ partial melting in metapelitic rocks, which was associated with the formation of garnet‐bearing aplites and associated pegmatites, occurred around Fraserburgh, where shear fabrics are absent. Thus, the rocks preserve a continuous metamorphic field gradient that straddles the shear zone network. This observation supports an alternative interpretation that anatexis was the result of mid‐Ordovician (Grampian) metamorphism, rather than an older tectonothermal event, and that the Inzie Head gneisses are autochthonous. Using an average mid‐Dalradian pelite as a plausible representative protolith, phase equilibria modelling satisfactorily reproduces the observed appearance and disappearance of key minerals providing that peritectic garnet produced with the first formed melts (represented by the garnet‐bearing aplites) depleted the source rocks in Mn. The modelled metamorphic field gradient records a temperature increase of at least 150 °C (from ~650 °C near Fraserburgh to in excess of 800 °C at Inzie Head) but is isobaric at pressures of 2.7–2.8 kbar, suggesting the Buchan Anticline developed synchronous with partial melting. The Buchan Anticline is likely an expression of crustal thinning and asthenospheric upwelling, which produced voluminous gabbroic intrusions that supplied the heat for Buchan metamorphism.  相似文献   

富F熔体-溶液流体体系的地球化学性状及成矿效应研究进展   总被引：1，自引：0，他引：1       下载免费PDF全文

赵博  张德会  张荣臻  石成龙 《地质科学》2015,50(1):222-240

F既是重要的岩浆挥发分,又是重要的助熔剂和矿化剂,同时也是克拉克值较大的元素之一,并且在(铝)硅酸盐熔体中高度可溶。本文从F的常见工业矿物和主要赋存形式、分配行为的多样性、对其它元素分配行为的影响、矿化作用(即亲氟元素在热液体系中的氟化物络合形式、存在环境和沉淀机制等)、萤石和冰晶石的溶解及沉淀机制以及富F岩浆一热液体系的成矿专属性及特征6个方面探讨了F的地球化学成矿作用。结论认为:F必须有能力大量进入与花岗质或伟晶岩质熔体共存的含水流体相中才具有进一步的成矿学意义,云英岩化、钠长石化、含黄玉—萤石石英脉、具有较高F/CaO比值的残余熔体以及F在高度演化花岗质岩浆中的过饱和等因素均可能导致含矿富F热液的出溶;但总体上,富F岩浆—热液体系具有成矿专属性的原因之一仍在于:F首先通过对熔体物理化学性质的影响间接支配着高场强亲氟元素如W、Sn、Nb、Ta、REE、U等的热液成矿效应。  相似文献   

伴随对流层中低层气温持续下降的雪转雨过程分析   总被引：2，自引：0，他引：2  

李海军  张雪慧  潘士雄 《气象科技》2015,43(6):1164-1169

利用欧洲中期天气预报中心（ECMWF）0.25°×0.25°分辨率细网格模式产品、探空观测资料和风廓线雷达等资料,对2014年2月18日浙江嘉兴雨雪天气过程中降水相态先由雨转雪、再由雪转雨的变化条件进行了分析,并对ECMWF细网格模式产品进行了预报性能检验,结果表明：模式形势预报准确,但未能预报出雪转雨过程。在对流层中低层气温持续降低的情况下,水汽凝结高度不同是造成两次相态转换的主要原因。上午垂直运动加强,水汽充沛,降水粒子的凝结高度高,足以形成大的雪花,在较低的零度层高度以下降落时不至于融化;下午垂直运动减弱,水汽集中在低层,尽管这一高度层的气温在-3～-2 ℃,但是不足以凝结成固态降水,同时地面气温受海上暖平流影响而回升,因此降水相态由雪转雨。  相似文献